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91Ó°ÊÓ

Assign formal charges to the atoms in each of the following molecules:

a.

b.

c.

Short Answer

Expert verified

a.

The formal charge on all H in CH3is 0

The formal charge on C in CH3is 0

The formal charge on O is -1

The formal charge on N is +1

b.

The formal charge on all H in CH3 is 0

The formal charge on C in CH3 is 0

The formal charge on N at left is -1

The formal charge on N in the middle is +1

The formal charge on N at the rightmost is 0.

c.

The formal charge on all H in CH3 is 0.

The formal charge on C in CH3 is 0.

The formal charge on N at left is 0.

The formal charge on N in the middle is +1.

The formal charge on N at the rightmost is -1.

Step by step solution

01

Formal charge

The formal charge is the electric charge present on an atom in a molecule. It indicates magnitude and charge, positive or negative.

02

Calculation of formal charge

The formal charge on an atom is equal to the number of valence electrons in a neutral and isolated atom minus the number of electrons present in its bonded atom form in a molecule. The number of electrons in a bonded atom is calculated as half the number of bonding electrons plus the nonbonding, that is, lone-pair electrons.

Formalcharge=Numberofvalenceelectronsinfreeatom−Numberofvalenceelectronsinbondedatom=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

03

. Calculation of formal charge on all H in CH3

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=1−22+0=1−1=0

04

(a) Calculation of formal charge on N

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−82+0=5−4=1

05

Calculation of formal charge on O

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=6−22+6=6−7=−1

06

Calculation of formal charge on all C in CH3

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=4−82+0=4−4=0


07

 (b) Calculation of formal charge on N bonded with  CH3

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−42+4=5−6=−1

08

Calculation of formal charge on N in the middle

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−82+0=5−4=1

09

Calculation of formal charge on all C in CH3

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=4−82+0=4−4=0

10

Calculation of formal charge on rightmost N

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−62+2=5−5=0

11

 (C):   Calculation of formal charge on N bonded with  CH3

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−22+4=5−5=0

12

Calculation of formal charge on N in the middle

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−82+0=5−4=1

13

Calculation of formal charge on all C in CH3

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=4−82+0=4−4=0

14

Calculation of formal charge on the rightmost N

Using the above formula:

Formalcharge=Numberofvalenceelectroninfreeatom−Numberofbondingelectron2+Numberofnonbondingelectron

=5−42+4=5−6=−1

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