Chapter 29: Q40. (page 1193)
What alkyl halide is needed to synthesize each amino acid from diethyl acetamidomalonate: (a)Asn; (b)His; (c)Trp?
Short Answer



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Chapter 29: Q40. (page 1193)
What alkyl halide is needed to synthesize each amino acid from diethyl acetamidomalonate: (a)Asn; (b)His; (c)Trp?



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What aldehyde is needed to synthesize each amino acid by the Strecker synthesis?
(a) Valine;
(b) Leucine;
(c) Phenylalanine.
Draw the structure of the N-phenylthiohydantoin formed by initial Edman degradation of each peptide: (a) Ala-Gly-Phe-Phe; (b) Val-Ile-Tyr.
Draw the organic products formed in each reaction.
a.

b.

Draw the structure for each peptide:
(a) Phe–Ala;
(b) Gly–Gln;
(c) Lys–Gly;
(d) R-H
Question: For the tetra peptide Asp–Arg–Val–Tyr:
a. Name the peptide using one-letter abbreviations.
b. Draw the structure.
c. Label all amide bonds.
d. Label the N-terminal and C-terminal amino acids
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