Chapter 12: Q 11 P (page 383)
Question: Where might the following compound have IR absorptions?

Short Answer
Absorption bands seen at 2210-2260 , 1690 and 1640-1680 .
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Chapter 12: Q 11 P (page 383)
Question: Where might the following compound have IR absorptions?

Absorption bands seen at 2210-2260 , 1690 and 1640-1680 .
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Write molecular formulas for compounds that show the following molecularions in their high-resolution mass spectra, assuming that C, H, N,and O might be present. The exact atomic masses are: 1.00783(1H), 12.00000(12C) , 14.00307 (14N) , 15.99491(16O) .
(a) M+ = 98.0844
(b) M+= 123.0320
Question: Where might the following compound have IR absorptions?

In light of the nitrogen rule mentioned in Problem 12-17, what is themolecular formula of pyridine, M+=79?
Question: Ketones undergo a reduction when treated with sodium borohydride, .What is the structure of the compound produced by reactionof 2-butanone with if it has an IR absorption at andin the mass spectrum?

Question: The mass spectrum (a) and the infrared spectrum (b) of another unknown hydrocarbon are shown. Propose as many structures as you can.


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