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How could you convert each of the following compounds into butanoic acid? Write each step showing the reagents needed.

(a) 1-Butanol

(b) 1-Bromobutane

(c) 1-Butene

(d) 1-Bromopropane

(e) 4-Octene

Short Answer

Expert verified

The conversion of the compounds into butanoic acid can be explained.

Step by step solution

01

Conversion of 1-Butanol into butanoic acid

The primary alcohol is 1-butanol. There is an oxidation to butanoic acid when treated with aqueous acid of CrO3. The steps involved are,

CH3CH2CH2CO2OH→H3O+CrO3CH3CH2CH2CO2H

02

Conversion of 1-Bromobutane into butanoic acid

There is a conversion of 1-bromobutane into 1-butanol. The primary alcohol is 1-butanol. There is an oxidation to butanoic acid when treated with aqueous acid of CrO3. The steps involved are,

CH3CH2CH2CH2Br→NaOHCH3CH2CH2CH2OH→H3O+CrO3CH3CH2CH2CO2H

03

Conversion of 1-Butene into butanoic acid

When there is a hydroboration of 1-Butene into BH3, The following is the Anti-Markovnikov region chemistry. There is an oxidation to butanoic acid when treated with aqueous acid of CrO3. The steps involved are,

CH3CH2CH=CH2→2.H2O2,O-H1.BH3,THFCH3CH2CH2CH2OH→H3O+CrO3CH3CH2CH2CO2H

04

Conversion of 1-Bromopropane into butanoic acid

There is a yield of butanenitrile by bromide ion replacement using cyanide ion. The nitrile hydrolysis using aqueous acid will yield botanic acid. The steps involved are,

CH3CH2CH2Br→2.H3O+1.NaCNCH3CH2CH2CO2H

05

Conversion of 4-Octene into butanoic acid

The symmetrical alkene is 4-Octene. There is a breakage of a double bond between C4 and C5 for the yield of butanoic acid molecules when it is acidified with KMnO4. The steps involved are,

CH3CH2CH2CH=CHCH2CH2CH3→H3O+KMnO42CH3CH2CH2CO2H

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