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Chapter 15: Q37. (page 570)

Question: What alkane is needed to make each alkyl halide by radical halogenation?

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01

Radical halogenation

The halogenation reaction involving the replacement of a highly reactive hydrogen atom of alkanes or alkyl substituted aromatics by any of the halide ions initiated by either heat or UV light is known as the radical halogenation reaction.

02

Identifying alkanes

The given alkyl halides are produced by the free-radical halogenation of the following compounds:


a) Replacing the bromide ion by hydrogen atom would give the corresponding alkane.


2-methyl butane

b) The halide ion is replaced by a hydrogen atom to form the corresponding hydrocarbon

Propyl cyclohexane

c) The chloride ion is replaced by the hydrogen atom to form the corresponding alkane.

2,2-Dimethyl propane

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Most popular questions from this chapter

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Question: The triphenylmethyl radical is an unusual persistent radical present in solution in equilibrium with its dimer. For 70 years the dimer was thought to be hexaphenylethane, but in 1970, NMR data showed it to be A.

a. Why is the triphenylmethyl radical more stable than most other radicals?

b. Use curved arrow notation to show how two triphenylmethyl radicals dimerize to form A.

c. Propose a reason for the formation of A rather than hexaphenylethane.d. How could 1 H and 13C NMR spectroscopy be used to distinguish between hexaphenylethane and A?
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