Chapter 15: Q18. (page 570)
Question: Draw all constitutional isomers formed when each alkene is treated with NBS + hν.
a.

b.

c.

Short Answer
Answer
a.

b.

c.

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Chapter 15: Q18. (page 570)
Question: Draw all constitutional isomers formed when each alkene is treated with NBS + hν.
a.

b.

c.

Answer
a.

b.

c.

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Questions: Why is a benzylic C-H bond unusually weak?
Question: In the presence of a radical initiator (Z* ), tributyltin hydride ( R3SnH,R=CH3CH2CH2CH2 ) reduces alkyl halides to alkanes: R'X+R3SnHR'H+R3SnX. The mechanism consists of a radical chain process with an intermediate tin radical:

This reaction has been employed in many radical cyclization reactions. Draw a stepwise mechanism for the following reaction.

Question: Draw the products formed when each alkene is treated with NBS + hv .
a.

b.

c.

Question: Draw the products formed when a chlorine atom reacts with each species.
a.
b.
c.
d. O2
Question: Which compounds can be prepared in good yield by allylic halogenation of an alkene?
a.

b.

c.

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