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Chapter 15: Q29. (page 570)

Question: Draw all resonance structures of the radical that results from abstraction of a hydrogen atom from the antioxidant BHA (butylated hydroxy anisole).

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01

Resonance structures

The resonance hybrid, which is the contributing structure of several structures, are indicated at the end while noting down the resonance structure of a particular compound.

02

Butylated hydroxyl anisole(BHA)

Butylated hydroxyl anisole comprises a combination of two isomeric alcohols. They are obtained from the compounds 4-methoxyphenol and isobutylene.

03

 Step 3: Resonance structures of the radical that results from the abstraction of hydrogen atom from the antioxidant BHA

Resonance structures are a way of describing the electron delocalization in a particular molecule. The resonance structures that result from the abstraction of the hydrogen atom from the antioxidant BHA can be given as:

Resonance structures of the radical that results from the abstraction of the hydrogen atom from the antioxidant BHA

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(b) What is the structure of C?

Question: When HBr adds to (CH3)2C=CH2 under radical conditions, two radicals are possible products in the first step of chain propagation. Draw the structure of both radicals and indicate which one is formed. Then draw the preferred product from HBr addition under radical conditions.
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