Chapter 15: Q19. (page 570)
Question: Draw the structure of the four allylic halides formed when 3-methylcyclohexene undergoes allylic halogenation with NBS + hν.
Short Answer
Answer

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Chapter 15: Q19. (page 570)
Question: Draw the structure of the four allylic halides formed when 3-methylcyclohexene undergoes allylic halogenation with NBS + hν.
Answer

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Question: Classify each radical as Primary , secondary or tertiary carbon radicals .
Question: Devise a synthesis of each compound using CH3CH3 as the only source of carbon atoms. You may use any other required organic or inorganic reagents.
a.

b.

c.

d.

Question: Using Mechanism 15.1 as a guide, write the mechanism for the reaction of CH4with Br2 to form CH3 Br and HBr. Classify each step as initiation, propagation, or termination.
Question: Reaction of (CH3 )3 CH with Cl2 forms two products: (CH3 )2 CHCH2Cl (63%) and (CH3)3 CCl (37%). Why is the major product formed by cleavage of the stronger 1° C-H bond?
Question: Which C-H bond is most readily cleaved in linoleic acid? Draw all possible resonance structures for the resulting radical. Draw all the hydroperoxides formed by the reaction of this resonance stabilized radical with O2.

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