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Chapter 8: Q. 52a E (page 262)

Show the structures of alkenes that give the following products on oxidative cleavage with in acidic solution:


a.CH3CH2CO2H+CO2

Short Answer

Expert verified
  1. But-1-ene

Step by step solution

01

Oxidation by KMnO4

KMnO4is a strong oxidising agent. In oxidative cleavage,KMnO4leads to the formation of 1,2-diol which leads to formation of the carboxylic acid andKMnO4is converted to brown MnO2.

The colour changes from purple to brown and diol lead to produce two adjacent alcoholic groups

02

Structure of alkene while undergoing oxidation

  1. Formation ofCH3CH2CO2H+CO2

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Most popular questions from this chapter

What products would you expect from oxymercuration-demercuration of the following alkenes?

a)

b)

Compound A has the formula C10H16. On catalytic hydrogenation over palladium, it reacts with only 1 molar equivalent of H2. Compound A also undergoes reaction with ozone, followed by zinc treatment, to yield a symmetrical diketone, B(C10H16O2).

How many rings does A have?

Question:What product will result from hydroboration鈥搊xidation of 1-methylcyclopentene with deuterated borane,? Show both the stereochemistry (spatial arrangement) and the regiochemistry (orientation) of the product.

What products would you expect from oxymercuration-demercuration of the following alkenes?

a)

b)

What alkenes might be used to prepare the following alcohols by hydroboration-oxidation?
See all solutions

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