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Chapter 15: Q15-13E (page 477)

Give IUPAC names for the following substances (red 5 O, blue 5 N):

Short Answer

Expert verified
  1. m-isopropyl phenol
  2. o-nitrobenzoic acid

Step by step solution

01

IUPAC nomenclature

It is a method to give a scientific name to the organic compounds recommended by the Indian Union of Pure and Applied Chemistry.

02

Nomenclature of benzene

IUPAC rules used for naming of benzene

  1. Name the parent aromatic benzene ring
  2. Assign numbering to the substituents
  3. Assign the first number to the bulky group
  4. Halogens get the priority
  5. Write the name of the molecule in alphabetic
03

To identify the IUPAC from the structure of compound A

  1. The parent ring is a benzene ring attached with OH so phenol
  2. Isopropyl is present at the meta position to the OH group
  3. So, IUPAC's name is m-isopropyl phenol
  4. So, the structure must be:

04

To identify the IUPAC from the structure of compound B

  1. The parent ring is a benzene ring attached with COOH which is acid so benzoic acid
  2. The Nitro group is present at the ortho position to the COOH group
  3. So, IUPAC name is o-nitro benzoic acid
  4. So, the structure must be:

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Most popular questions from this chapter

The compound below is the product initially formed in a Claisen rearrangement (Section 18-4). This product is not isolated but tautomerizes to its enol form. Give the structure of the enol and provide an explanation as to why the enol tautomer is favored.

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Give IUPAC names for the following compounds

a)

Draw structures corresponding to the following IUPAC names:

(a) p-Bromochlorobenzene

(b) p-Bromotoluene

(c) m-Chloroaniline

(d) 1-Chloro-3,5-dimethylbenzene

The substitution reaction of toluene with Br2 can, in principle, lead to the formation of three isomeric Bromo toluene products. In practice, however, only o- and p-Bromo toluene are formed in substantial amounts. The meta isomer is not formed. Draw the structures of the three possible carbocation intermediates (Problem 15-51), and explain why ortho and para products predominate over meta products.
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