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Chapter 15: Q 15-15-18 E-e (page 451)

Give IUPAC names for the following compounds

e)

Short Answer

Expert verified

e)

1-fluoro-2,4-dinitrobenzene

Step by step solution

01

What is IUPAC?

In chemistry, the naming of organic compounds follows the rules set out by IUPAC (International Union of Pure and Applied Chemistry).

02

IUPAC name of compound

In the provided compound e, the name of the parent hydrocarbon is benzene. Numbering the ring in such a way that the functional group and substituent get the lowest possible number.

03

Position of functional group in compound

The fluorine group is at the first carbon, the nitro group is at the second and fourth carbon atom. Thus, the IUPAC name of the compound is 1-fluoro-2,4dinitrobenzene represented as:

1-fluoro-2,4-dinitrobenzene

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Most popular questions from this chapter

Look at the three resonance structures of naphthalene shown in Section 15-6, and account for the fact that not all carbon-carbon bonds have the same length. The C1鈥揅2 bond is 136 pm long, whereas the C2鈥揅3 bond is 139 pm long

To be aromatic, a molecule must have 4n+2 p electrons and must have a planar, monocyclic system of conjugation. Cyclodecapentaene fulfills one of these criteria but not the other and has resisted all attempts at synthesis. Explain.

Look at the five resonance structures for phenanthrene (Problem 15-26), and predict which of its carbon-carbon bonds is the shortest.

Propose structures for compounds that fit the following descriptions:

(a) C10H141HNMR: 7.18鈥�未(4 H, broad singlet);2.70鈥�未(4 H, quartet, J = 7 Hz); 1.20鈥�未(6 H, triplet, J =7 Hz) IR:745鈥�cm-1.

(b)C10H141HNMR:7.0鈥�未(4 H, broad singlet);2.85鈥夆赌�未(1 H, septet, J = 8 Hz);2.28鈥夆赌�未(3 H, singlet);1.20鈥夆赌�未(6 H, doublet, J = 8 Hz) IR:825鈥�cm-1.

Cycloheptatrienone is stable, but cyclopentadienone is so reactive that it can鈥檛 be isolated. Explain, taking the polarity of the carbonyl group into account.

Cycloheptatrienone Cyclopentadienone
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