Explanations 
Textbooks 
Flashcards 
91影视 AI 
Notes 
Study Plans 
Study Sets 
Find a degree 
Magazine Chapter 6: 18. (page 149)
Draw the more stable chair conformation of the following molecules, and estimate the amount of strain in each:
Short Answer
The more stable chair conformation is given below and 2 kJ/mol strain is present.
Step by step solution
Chair conformation
Chair conformation structure for six-membered ring is when atoms 2, 3, 5, and 6 lie in the same plane, atom 1 lies above the plane, and atom 4 lies below the plane.
Axial and equatorial positions
Axial bonds are the bonds that are perpendicular or vertical to the ring plane. Equatorial bonds are approximately horizontal in the plane of the ring.
Energy difference
The energy difference between axial and equatorial conformations is due to steric strain caused by 1,3-diaxial interactions. The axial group on C1 is too close to the axial hydrogens three carbons away on C3 and C5, resulting in the steric strain.
Similarly, the axial group on C2 is too close to the axial hydrogens three carbons away on C4 and C6, resulting in the steric strain.
Chair conformations possible and strain calculation
Conformation one possible
In this image, it can be seen thatinteractions are present.
One interaction of gives 3.8 kJ/mol energy and here two interactions are present giving 7.6 kJ/mol strain.
Conformation two possible
In this image, it can be seen thatinteractions are present.
One interaction of gives 1 kJ/mol energy and here two interactions are present giving 2 kJ/mol strain.
More stable chair configuration
Hence, it can be seen this structure has less strain and is hence more stable.
Conformation two more stable
Over 30 million students worldwide already upgrade their learning with 91影视!
