91影视

Infrared and mass spectroscopy aretwo important tools for a chemist to examine molecular compound.

Spectroscopy is the 鈥渓ens of a forensic investigation鈥� as they detect the chemical compound by molecular analysis.

The given compound is 2-isobutylcyclopentanone.

2-isobutylcyclopentanone has the 5-membered ring, thus giving the only IR absorption at 1750${\text{cm}}^{\text{-1}}$.

2-isobutylcyclopentanone shows mass spectra as follows:

• The product of alpha cleavage, which occurs at the ring having the same mass as the molecular ion, gives the peak at m/z = 140
• The charged fragment result from Mc Lafferty rearrangement gives the peak at m/z = 84.

The m/z value due to alpha cleavage and Mc Lafferty rearrangement is shown below.

2-isobutylcyclopentanone m/z values