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Chapter 6: Problem 6.28 (page 241)

Classify each transformation as substitution, elimination, or addition.

a.

b.

Short Answer

Expert verified

Answer

  1. Elimination reaction
  2. Addition reaction

Step by step solution

01

Step-by-Step SolutionStep 1: Substitution Reaction

The reactions that involve the replacement/substitution of a group or atom by another is termed substitution reaction.

02

Addition and Elimination Reactions

The addition of atoms or groups of atoms to a substrate is termed an addition reaction, and the removal or elimination of atoms/groups of atoms from a substrate is termed an elimination reaction.

03

Classifying the given reactions

a. The reaction 鈥榓鈥� involves the elimination of H2OH+OHfrom the starting material leading to the formation of a pi bond in the product.


Elimination reaction in a.

Therefore, the given reaction is an elimination reaction.

b. The given reaction involves the addition of hydrogen and a hydroxyl group to the carbonyl carbon leading to the conversion of the pi bond to two sigma bonds.

Addition reaction in b.

The given reaction is an addition reaction.

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Most popular questions from this chapter

Compound A can be converted to either B or C. The energy diagrams for both processes are drawn on the graph below.

  1. Label each reaction as endothermic or exothermic.
  2. Which reaction is faster?
  3. Which reaction generates the product lower in energy?
  4. Which points on the graphs correspond to transition states?
  5. Label the energy of activation for each reaction.
  6. Label the 鈭�H掳 for each reaction.

Use the values in Table 6.2 to calculatefor each reaction. Classify each reaction as endothermic or exothermic.

a.

b.

Which value (if any) corresponds to a faster reaction: (a) Ea=40kJ/molor Ea=4kJ/mol; (b) a reaction temperature of 0掳C or a reaction temperature of 25掳C; (c) Keq=10or Keq=100; (d) role="math" localid="1648275832528" 鈭�H=-10kJ/molor 鈭�H=10kJ/mol ?

Use curved arrows to show the movement of electrons in each equation.

a.

b.

The following is a concerted, bimolecular reaction:CH3+NaCN鈫�CH3CN+NaBr.

a. What is the rate equation for this reaction?

b. What happens to the rate of the reaction if[CH3Br] is doubled?

c. What happens to the rate of the reaction if [NaCN] is halved?

d. What happens to the rate of the reaction if [CH3Br] and [NaCN] are both increased by a factor of five?
See all solutions

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