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Question: Considering each of the following values and neglecting entropy, tell whether the starting material or product is favored at equilibrium:

(a) Δ±á°=80kJ/mol

(b) Δ±á°=-40kJ/mol

Short Answer

Expert verified

Answer

(a) Starting material is favored at equilibrium.

(b) Products are favored at equilibrium.

Step by step solution

01

Step-by-Step SolutionStep 1: Relation between ΔG°and ΔH°  

Δ³Ò°corresponds to the change in free energy, Δ±á°corresponds to the enthalpy change, and Δ³§Â° represents the change in entropy.

width="134" height="22" role="math">Δ³Ò°=Δ±á°+TΔ³§

02

Estimating the sign of ΔG°

The free energy change of a reaction can be estimated/approximated using the change in the bonding energy i.e., the change in enthalpy.

Δ³Ò°≈Δ±á°

The free energy change for favorable reactions (the reactions that favors product formation) is always negative.

03

ΔH° for chemical reactions

Since Δ±á°is directly related to Δ³Ò°, a negative value of Δ±á°indicates that the reaction favors products, and a positive value of Δ±á°indicates that the reaction favors the reactants (starting material).

04

Predicting the direction of a reaction using ΔH° values

In the given case the reaction favors starting material as the value of Δ±á°is positive.

The negative value of indicates that the reaction favors products at equilibrium.

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