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Answer Problem 6.14 for a reaction with Δ±á°=-20kJ/mol.

Short Answer

Expert verified

Answer

  1. True.
  2. False; Δ³Ò°for the reaction is negative.
  3. True.
  4. False; The bonds in the starting materials are weaker than the bonds in the product.
  5. True.

Step by step solution

01

Step-by-Step SolutionStep 1: Predicting feasibility of a reaction

The feasibility of a reaction (i.e., whether the reaction favors product formation) can be predicted using the Δ±á°and Δ³Ò°.

A negative value of role="math" localid="1648269334522" Δ±á°and Δ³Ò°indicates that the reaction favors the product formation.

02

Equilibrium constant

Equilibrium constant ( Keq) is determined by the ratio of the amount of products to that of the reactants.

Keq>1 signifies that the reaction favors the products.

Keq<1signifies that the reaction favors the reactants.

03

True or False

(a) The reaction is exothermic – True.

The negative value of Δ±á°indicates that the reaction is exothermic.

(b)Δ³Ò° for the reaction is positive – False.

Since Δ±á° is directly related to Δ³Ò°, the value of Δ³Ò° for the reaction should be negative.

(c) Keqis greater than 1 – True.

Negative value of Δ±á° signifies that the products are favored, and in the reactions favoring products the value of the equilibrium constant is always greater than 1.

(d) The bonds in the starting materials are stronger than the bonds in the product – False.

A negative value of Δ±á°indicates that the reaction favors the products and therefore the bonds in the starting material should be weaker than the bonds in the product.

(e) The product is favored at equilibrium – True.

The products are favored at equilibrium as ∆H° is negative.

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Most popular questions from this chapter

Consider the following energy diagram for the conversion of A→G.

a. Which points on the graph correspond to transition states?

b. Which points on the graph correspond to reactive intermediates?

c. How many steps are present in the reaction mechanism?

d. Label each step of the mechanism as endothermic or exothermic.

e. Label the overall reaction as endothermic or exothermic.

The following is a concerted, bimolecular reaction:CH3+NaCN→CH3CN+NaBr.

a. What is the rate equation for this reaction?

b. What happens to the rate of the reaction if[CH3Br] is doubled?

c. What happens to the rate of the reaction if [NaCN] is halved?

d. What happens to the rate of the reaction if [CH3Br] and [NaCN] are both increased by a factor of five?

For a reaction with Δ±á°=40kJ/mol, decide which of the following statements is (are) true. Correct any false statement to make it true. (a) Δ³Ò°The reaction is exothermic; (b) for the reaction is positive; (c) Keq is greater than 1; (d) the bonds in the starting materials are stronger than the bonds in the product; and (e) the product is favored at equilibrium.

Calculate Δ±á° for each reaction.

  1. HO·+CH4→.CH3+H2O
  2. CH3OH+HBr→CH3Br+H2O

The Diels–Alder reaction, a powerful reaction discussed in Chapter 16, occurs when a 1,3- diene such as A reacts with an alkene such as B to form the six-membered ring in C.

a. Draw curved arrows to show how A and B react to form C.

b. What bonds are broken and formed in this reaction?

c. Would you expect this reaction to be endothermic or exothermic?

d. Does entropy favor the reactants or products?

e. Is the Diels–Alder reaction a substitution, elimination, or addition?

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