Chapter 5: Q.3 (page 180)
Draw the mirror image of each compound. Label each molecule as chiral or achiral.

a.

b.

c.

d.
Short Answer
a. Achiral

b. Chiral

c. Achiral


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Chapter 5: Q.3 (page 180)
Draw the mirror image of each compound. Label each molecule as chiral or achiral.

a.

b.

c.

d.
a. Achiral

b. Chiral

c. Achiral


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Draw both enantiomers of clopidogrel (trade name Plavix), a drug given to prevent the formation of blood clots in persons who have a history of stroke or coronary artery disease. Plavix is sold as a single enantiomer with the S configuration. Which enantiomer is Plavix?

An acid鈥揵ase reaction of (R)-sec-butylamine with a racemic mixture of 2-phenylpropanoic acid forms two products having different melting points and somewhat different solubilities. Draw the structure of these two products. Assign R and S to any stereogenic centers in the products. How are the two products related? Choose from enantiomers, diastereomers, constitutional isomers, or not isomers.

Consider Newman projections (A鈥揇) for four-carbon carbohydrates. How is each pairof compounds related: (a) A and B; (b) A and C; (c) A and D; (d) C and D? Choose fromidentical molecules, enantiomers, or diastereomers.

Draw in a plane of symmetry for each molecule.

a.

b.

c.

d.
A molecule is achiral if it has a plane of symmetry in any conformation. Each of the following conformations does not have a plane of symmetry, but rotation around a carbon鈥揷arbon bond forms a conformation that does have a plane of symmetry. Draw this conformation for each molecule.

a.

b.
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