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Chapter 5: Q.3 (page 180)

Draw the mirror image of each compound. Label each molecule as chiral or achiral.

a.

b.

c.

d.

Short Answer

Expert verified

a. Achiral

b. Chiral

c. Achiral

d. Chiral

Step by step solution

01

Chiral molecule

Chiral molecules are the molecules that have 鈥渘on-superimposable mirror images.鈥�

Molecules having one stereogenic center are always chiral.

02

Achiral molecules

The molecules that have superimposable mirror images are termed achiral.

Achiral molecules have no stereogenic centers.

03

Chiral and achiral molecules

The mirror images of the given compounds are as follows:

a.

The mirror image of compound a

The mirror images are superimposable on each other and hence the compound is achiral.

b.

The mirror image of compound b

The given molecule consists of a stereocenter and its mirror images are non-superimposable.

Therefore, the compound is chiral.

c.

The mirror image of compound c

The mirror images are identical to each other and hence are superimposable.

Therefore, the compound is achiral.

d.

The mirror image of compound d

The given compound is chiral as it consists of a stereocenter (the carbon atom bonded to fluorine) and its mirror images are non-superimposable.

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Most popular questions from this chapter

For the given ee values, calculate the percentage of each enantiomer present.

a. 90% ee

b. 99% ee

c. 60% ee

How are the compounds in each pair related to each other? Are they identical, enantiomers, diastereomers, constitutional isomers, or not isomers of each other?

a.

and

b.

and

c.

and

d.

and

e.

and

f.

and

Locate the stereogenic centers in each molecule. Compounds may have one or more stereogenic centers.

a.

b.

c.

d.

e.

f.

An acid鈥揵ase reaction of (R)-sec-butylamine with a racemic mixture of 2-phenylpropanoic acid forms two products having different melting points and somewhat different solubilities. Draw the structure of these two products. Assign R and S to any stereogenic centers in the products. How are the two products related? Choose from enantiomers, diastereomers, constitutional isomers, or not isomers.

a. Label the four stereogenic centres in sorbitol as R or S.

b. How are sorbitol and A related?

c. How are sorbitol and B related?
See all solutions

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