Chapter 5: Q.11 (page 187)
Which group in each pair is assigned the higher priority?
a.
b.
c.
d.
e. localid="1648296449951"
f.
Short Answer
a.
b.
c.
d.
e.
f.
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Chapter 5: Q.11 (page 187)
Which group in each pair is assigned the higher priority?
a.
b.
c.
d.
e. localid="1648296449951"
f.
a.
b.
c.
d.
e.
f.
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If the two stereogenic centers of a compound are R,S in configuration, what are the R,S assignments for its enantiomer and two diastereomers?
Give the IUPAC name for each compound, including the R,S designation for each stereogenic center.

a.

b.

c.
Determine if each compound is identical to or an enantiomer of A.


a.

b.

c.
For the given ee values, calculate the percentage of each enantiomer present.
a. 90% ee
b. 99% ee
c. 60% ee
The amino acid (S)-alanine has the physical characteristics listed under the structure.

a. What is the melting point of (R)-alanine?
b. How does the melting point of a racemic mixture of (R)- and (S)-alanine compare to the melting point of (S)-alanine?
c. What is the specific rotation of (R)-alanine, recorded under the same conditions as the reported rotation of (S)-alanine?
d. What is the optical rotation of a racemic mixture of (R)- and (S)-alanine?
e. Label each of the following as optically active or inactive: a solution of pure (S)-alanine; an equal mixture of (R)- and (S)-alanine; a solution that contains 75% (S)- and 25% (R)-alanine.
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