Chapter 12: PROBLEM 12.33 (page 487)
Question: Draw the organic products formed when each alkene is treated with H2 / Pd-C. Indicate the three-dimensional structure of all stereoisomers formed.
a.

b.

c.

Short Answer
Answer
a.

b.

c.

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Chapter 12: PROBLEM 12.33 (page 487)
Question: Draw the organic products formed when each alkene is treated with H2 / Pd-C. Indicate the three-dimensional structure of all stereoisomers formed.
a.

b.

c.

Answer
a.

b.

c.

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Question: One step in the degradation of fats involves the reaction of (R)-glycerol phosphate with NAD+ in the presence of the enzyme glycerol phosphate dehydrogenase. What products are formed if reaction occurs only at the 2° alcohol.

Question: Draw the organic products formed when allylic alcohol A is treated with each reagent.
a. H2 +Pd-c
b. mCPBA
c. PCC
d. CrO3 ,H2SO4, H2O
e.(CH3)3COOH , Ti [OCH(CH3)3]4 (+) -DET
f.(CH3)3COOH , Ti [OCH(CH3)3]4 (-) -DET
g. [1] PBr3,[2] LiAlH4 ,[3] H2O
h. HCrO4- –Amberlyst A-26 resin

Question: Draw the products formed when both cis- and trans-but-2-ene are treated with a peroxyacid followed by – OH (in H2O ). Explain how these reactions illustrate that anti-dihydroxylation is stereospecific.
Question: Draw a stepwise mechanism for the following reaction.
Question: Draw the organic products formed in each reaction.
a.

b.

c.

d.

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