/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} PROBLEM 12.24 Question: Draw the organic produ... [FREE SOLUTION] | 91影视

91影视

Log out

Learning Materials

Features

Discover

Chapter 12: PROBLEM 12.24 (page 479)

Question: Draw the organic products in each of the following reactions.

a.

b.

c.

d.

Short Answer

Expert verified

Answer

a.

b.

c.

d.

Step by step solution

01

Oxidation using alcohols

Alcohols can be oxidized into ketones, aldehydes, or carboxylic acids using strong oxidizing agents.

The reactions of different types of alcohols with oxidizing agents are given below:

Oxidation of alcohols

02

Reagents

The reagents that are mostly used are PCC, CrO3 ,H2SO4 /H2SO4, K2Cr2O7

CrO3and K2Cr2O7 are stronger oxidizing agents and are therefore used to convert primary alcohols to carboxylic acids. Secondary alcohols are reactive to all of the reagents.

03

Determining the organic products

a. The given compound is a primary alcohol, which when oxidized with PCC, would produce an aldehyde, as shown below:

Oxidation of primary alcohol using PCC

b. As secondary alcohols get oxidized to form ketone in presence of any Cr6+ reagents, the product would be as shown below

Oxidation of secondary alcohol using PCC

c. When primary alcohol is reacted with , it will produce a carboxylic acid.

Oxidation of primary alcohol using CrO3

d. The secondary alcohol would react with to produce the following ketone.

Oxidation of secondary alcohol using

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Question: a) Draw the structure of a compound of molecular formula C6H10 that reacts with H2 in the presence of Pd-C but does not react with H2in the presence of Lindlar catalyst. (b) Draw the structure of a compound of molecular formula C6H10 that reacts with H2 when either catalyst is present

Question: An unknown compound A of molecular formula C10H18O reacts with H2SO4 to form two compounds (B and C) of molecular formula C10H16. B and C both react with H2 in the presence of Pd-C to form decalin. Ozonolysis of B forms D, and ozonolysis of C forms a diketone E of molecular formula C10H16O2. Identify the structures of compounds A, B, C and E.

Question: What alkene yields each set of oxidative cleavage products?

a.

b.

Question: It is sometimes necessary to isomerize a cis alkene to a trans alkene in a synthesis, a process that cannot be accomplished in a single step. Using the reactions that you have learned in Chapters 8鈥�12, devise a stepwise method to convert cis-but-2-ene to trans-but-2-ene.

Question: One compound that contributes to the 鈥渟eashore smell鈥漚t beaches in Hawai鈥檚 is dictyopterene D鈥� with excess H2in the presence of a Pd catalyst forms butylcycloheptane. Ozonolysis with O3 followed by (CH3)2S forms CH2(CHO)2,HCOCH2CH(CHO)2, and CH3CH2CHO. What are possible structures of dictyopterene D鈥�?

See all solutions

Recommended explanations on Chemistry Textbooks

Nuclear Chemistry

Read Explanation

Chemical Analysis

Read Explanation

Making Measurements

Read Explanation

Chemical Reactions

Read Explanation

Physical Chemistry

Read Explanation

Organic Chemistry

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.