Chapter 13: Q13-35E (page 419)
The following compounds all show a single line in their NMR spectra. List them in order of expected increasing chemical shift:
,cyclohexane ,,benzene
Short Answer
Increasing order is as follows:
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Chapter 13: Q13-35E (page 419)
The following compounds all show a single line in their NMR spectra. List them in order of expected increasing chemical shift:
,cyclohexane ,,benzene
Increasing order is as follows:
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Predict the splitting patterns you would expect for each proton in the following molecules:
How many types of non-equivalent protons are present in each of the following molecules?

How many absorptions would you expect (S)-malate, an intermediate in carbohydrate metabolism, to have in itsspectrum? Explain.

How many 13C NMR absorptions would you expect for cis-1,3-dimethylcyclohexane?For trans-1,3-dimethylcyclohexane? Explain.
The following 1H NMR absorptions were obtained on a spectrometer
operating at 300 MHz. Convert the chemical shifts from units to hertz
downfield from TMS.
(a)2.1(b)3.45(c)6.30(d)7.70
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