Chapter 12: Q66E (page 354)
Question: 21-66 Assign structures to compounds with the following 1H N MR spectra:


Short Answer
The structures to compounds with the following1H NMRspectra
a)

b)

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Chapter 12: Q66E (page 354)
Question: 21-66 Assign structures to compounds with the following 1H N MR spectra:


The structures to compounds with the following1H NMRspectra
a)

b)

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Question: Grignard reagents undergo a general and very useful reaction with
ketones. Methylmagnesium bromide, for example, reacts with cyclohexanoneto yield a product with the formula . What is the structure of this product if it has an IR absorption at ?

From what alkyne might each of the following substances have been made? (Green = Cl.)

Where might the following compounds have IR absorptions?

The amount of energy required to spin-flip a nucleus depends both on the strength of the external magnetic field and on the nucleus. At a field strength
of 4.7 T, rf energy of 200 MHz is required to bring a nucleus into resonance,
but energy of only 187 MHz will bring a nucleus into resonance. Calculate
the amount of energy required to spin-flip a nucleus. Is this amount greater
or less than that required to spin-flip a nucleus?
Assuming that strong acids add to alkynes in the same manner as they add to alkenes, propose a mechanism for each of the following reactions:

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