Chapter 16: Q53E (page 524)
What product(s) would you expect to obtain from the following
reactions?
(a)

(b)

(c)

(d)

Short Answer
Answer

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Chapter 16: Q53E (page 524)
What product(s) would you expect to obtain from the following
reactions?
(a)

(b)

(c)

(d)

Answer

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Rank the compounds in each of the following groups in order of their reactivity
to electrophilic substitution:
(a) Nitrobenzene, phenol, toluene, benzene
(b) Phenol, benzene, chlorobenzene, benzoic acid
(c) Benzene, bromobenzene, benzaldehyde, aniline
Triphenylmethane can be prepared by reaction of benzene and chloroform in the presence of . Propose a mechanism for the reaction.

How many products might be formed on chlorination of o-xylene (o-dimethylbenzene), m-xylene, and p-xylene?
Using resonance structures of the intermediates, explain why bromination of biphenyl occurs at ortho and para positions rather than at meta.

Question: Predict the major products of the following reactions:
(a) Nitration of bromobenzene
(b) Bromination of nitrobenzene
(c) Chlorination of phenol
(d) Bromination of aniline
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