Chapter 15: Q15-1P (page 455)
Tell whether the following compounds are ortho-, meta-, or para-disubstituted:

Short Answer
The name of the compounds are stated below
- meta-chloro toluene
- para-nitro chloro benzene
- ortho sulphonyl phenol
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Chapter 15: Q15-1P (page 455)
Tell whether the following compounds are ortho-, meta-, or para-disubstituted:

The name of the compounds are stated below
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Thiamin, or vitamin B1, contains a positively charged five-membered nitrogen–sulfur heterocycle called a thiazolium ring. Explain why the thiazolium ring is aromatic.

Propose a structure for a molecule that has the following NMR spectrum and has IR absorptions at 700, 740, and :

Azulene, an isomer of naphthalene, has a remarkably large dipole moment for a hydrocarbon (5 1.0 D). Explain, using resonance structures.

Draw all of the resonance forms for each. What patterns emerge?

The compound below is the product initially formed in a Claisen rearrangement (Section 18-4). This product is not isolated but tautomerizes to its enol form. Give the structure of the enol and provide an explanation as to why the enol tautomer is favored.

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