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Chapter 9: Q. 9-9-3 P-a (page 265)

What products would you expect from the following reactions?

a. CH3CH2CH2C鈮�CH+Cl2

Short Answer

Expert verified

a.

Step by step solution

01

Markovnikov reactions

In this the alkyne is converted to alkene by the halogenation that the three out of one triple bond is break foe the addition of halogen but the halogen are added always in trans geometry.

02

Reaction of alkyne with halide CH3CH2CH2C≡CH+Cl2

When alkyne reacts with halide they undergo an additional reaction to form a halogen-substituted alkene. Alkyne follows Markovnikov regiochemistry in which two added halogen atoms are always in a trans relationship with each other as shown:

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Most popular questions from this chapter

What products would you obtain by hydration of the following alkynes?

How would you prepare the following carbonyl compounds starting from an alkyne (reddish-brown Br)?

b.

Each of the following syntheses requires more than one step. How

would you carry them out?

(a)

(b)

How would you carry out the following conversions? More than one

step is needed in each case.

A hydrocarbon of unknown structure has the formula C8H10. On catalytic hydrogenation over the Lindlar catalyst, 1 equivalent of H2 is absorbed. On hydrogenation over a palladium catalyst, 3 equivalents of H2 are absorbed.

(a) How many degrees of unsaturation are present in the unknown structure?

(b) How many triple bonds are present?

(c) How many double bonds are present?

(d) How many rings are present?

(e) Draw a structure that fits the data.
See all solutions

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