91Ó°ÊÓ

Secondary alcohols can be converted to ketones in the presence of acidified ${\mathbf{CrO}}_{\mathbf{3}}$.The oxidation of a secondary aromatic alcohol in the presence of${\mathbf{KMnO}}_{\mathbf{4}}$ gives carboxylic acid. This gets reduced with lithium aluminium hydride to produce a primary alcohol.

(a) The compound 1-phenylethanol reacts with and to form acetophenone. The reaction can be given as:

Reaction (a)

(b)The compound, 1-phenylethanol reacts with and to form benzoic acid. This further reacts with and to form benzyl alcohol. The reaction can be given as:

Reaction (b)

(c) The compound, 1-phenylethanol reacts with and to form benzoic acid. This further reacts with and to form m-bromobenzoic acid. The reaction can be given as:

Reaction (c)

(d) The compound,1-phenylethanol reacts with and to form acetophenone. This further reacts with and to form 2-Phenyl-2-propanol. The reaction can be given as:

Reaction (d)