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Chapter 1: Q52. (page 55)

Question: Draw all reasonable resonance structures for each species.

a.O3-b.NO3-(acentralNatom)c.N3-

d.

e.

Short Answer

Expert verified

Answer

a.

b.

c.

d.

e.

Step by step solution

01

Step-by-Step Solution Step 1: Resonance structures

Resonance structures are contrasting in the position of double bonds and lone pairs of electrons. The position of the elements is unaltered.

02

The position of multiple bonds and lone pairs

The electrons move in the direction of multiple bonds, and the double bond also moves in the same direction. The lone pair's movement creates a double bond, and the movement of the double bond creates the electron density.

03

Resonance structures of the compounds

a. Ozone has two resonance structures. The position of multiple bonds and hence the lone pairs are interchanged to obtain the two resonance structures.


Representation of two resonance structures

b. NO3-has three resonance structures. The position of multiple bonds and hence the lone pairs are interchanged to obtain the three resonance structures.


Representation of three resonance structures

c. N3-has three resonance structures.


Representation of three resonance structures

e. Three resonance structures are obtained for the given compound.

Representation of three resonance structures

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Most popular questions from this chapter

Question: Use the observed bond lengths to answer each question. (a) Why is bond [1] longer than bond [2] (143 pm versus 136 pm)? (b) Why are bonds [3] and [4] equal in length (127 pm) and shorter than bond [2]?

Question: With reference to compound A drawn below, label each compound as an isomer, a resonance structure, or neither.

Question: When two carbons having different hybridizations are bonded together, the C-C bond contains a slight dipole. In a Csp2 - Csp3 bond, what is the direction of the dipole? Which carbon is considered more electronegative?

Question: How are the molecules or ions in each pair related? Classify them as resonance structures, isomers, or neither.

a. and

b. and

c. and

d. and

Question: Convert the following condensed formulas into skeletal structures:

a.CH3CONHCH3c.(CH3)COHe.CH3COCH2CO2Hb.CH3COCH2Brd.CH3COClf.HO2CCH(OH)CO2H
See all solutions

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