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Chapter 1: Q52. (page 55)

Question: Draw all reasonable resonance structures for each species.

a.O3-b.NO3-(acentralNatom)c.N3-

d.

e.

Short Answer

Expert verified

Answer

a.

b.

c.

d.

e.

Step by step solution

01

Step-by-Step Solution Step 1: Resonance structures

Resonance structures are contrasting in the position of double bonds and lone pairs of electrons. The position of the elements is unaltered.

02

The position of multiple bonds and lone pairs

The electrons move in the direction of multiple bonds, and the double bond also moves in the same direction. The lone pair's movement creates a double bond, and the movement of the double bond creates the electron density.

03

Resonance structures of the compounds

a. Ozone has two resonance structures. The position of multiple bonds and hence the lone pairs are interchanged to obtain the two resonance structures.


Representation of two resonance structures

b. NO3-has three resonance structures. The position of multiple bonds and hence the lone pairs are interchanged to obtain the three resonance structures.


Representation of three resonance structures

c. N3-has three resonance structures.


Representation of three resonance structures

e. Three resonance structures are obtained for the given compound.

Representation of three resonance structures

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Most popular questions from this chapter

Question:

a. What is the hybridization of each N atom in nicotine?

b. What is the geometry around each N atom?

c. In what type of orbital does the lone pair on each N atom reside?

d. Draw a constitutional isomer of nicotine.

e. Draw a resonance structure of nicotine.

Question: Use the ball-and-stick model to answer each question about carbidopa, a drug used in combination with l-dopa to treat Parkinson鈥檚 disease.

a. Draw a skeletal structure of carbidopa

b. Determine the hybridization around each carbon atom.

c. What is the hybridization and geometry around each N atom?

d. How many polar bonds are present?

Question: Assign formal charges to each carbon atom in the given species. All lone pairs have been drawn in.

a.

b.

c.

d.

Question: Answer the following questions about acetonitrile (CH3C鈮�N):

a. Determine the hybridization of both C and N atoms.

b. Label all bonds as 蟽or蟺 .

c. In what type of orbital does the lone pair on N reside?

d. Label all bonds as polar or nonpolar.

Question: Label each bond in the following compounds as ionic or covalent.

a.F2b.LiBrc.CH3CH3d.NaNH2e.NaOCH2
See all solutions

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