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Consider separate 1.0-L samples of O2(g) and He(g), both at 25oC and the same pressure. Compare the change in momentum per impact and the number of impacts per second in the two samples.

Short Answer

Expert verified

Answer: The change in momentum per impact is 2.827 times larger for O2 than for He. The number of impacts per second is 2.827 higher for He than O2.

Step by step solution

01

Meaning of change in momentum

For an elastic collision, the change in momentum per impact is given as:

(mu)=2mu

Where, m = mass, u = velocity

The above expression can also be written as:

2mu2TM

Where, T = temperature, M = molar mass

02

Comparison of the Change in momentum per impact

The proportion between the gases is given below:

(mu)O2(mu)He=2TMO22TMHe(mu)O2(mu)He=MO2MHe(mu)O2(mu)He=31.998gmol-14.003gmol-1(mu)O2(mu)He=2.827

Hence, the change in momentum per impact is 2.827 times larger for O2 than for He.

03

Comparison of the number of impacts per second

The impact rate can be calculated by using the following equation:

Z=ANVRT2蟺尘

The proportion between the impact rate for O2 and He is given below:

ZO2ZHe=ANVRT2蟺惭O2ANVRT2蟺惭HeZO2ZHe=1MO21MHeZO2ZHe=MHeMO2ZO2ZHe=4.003gmol-131.998gmol-1

ZO2ZHe=0.3527ZHeZO2=2.827

Hence, the number of impacts per second is 2.827 higher for He than O2.

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