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Chapter 26: Q 4. (page 1054)

Draw the product of each reaction.

Short Answer

Expert verified

Answer

a.

b.

c.

d.

Step by step solution

01

Suzuki reaction

A coupling reaction that follows a catalytic cycle involving oxidative addition, transmetalation, and reductive elimination is a Suzuki reaction.

02

Products

The Suzuki reaction of the given compounds would give the following compounds:

a. The vinyl iodide would react with the given organoborane to form the given conjugated diene.

Formation of conjugated diene

b. The organoborane would react with 1-bromobut-2-ene to form the given compound.

Formation of substituted benzene

c. Bromobenzene reacts with lithium in the presence of the organoborane to form a mixture of methoxylithium and another molecule of organoborane.

Formation of products

Ethynecyclohexane reacts with the organoborane to form the given compound.

Formation of the organoborane

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Most popular questions from this chapter

Devise a synthesis of each compound from benzene. You may also use any organic compounds having four carbons or fewer, and any required inorganic reagents.

a.

b.

Although diazomethane ( CH2N2) is often not a useful reagent for preparing cyclopropanes,other diazo compounds give good yields of more complex cyclopropanes. Draw a stepwisemechanism for the conversion of diazo compound A to B, an intermediate in the synthesis ofsirenin, the sperm attractant produced by the female gametes of the water mold Allomyces.

In addition to using CHX3and base to synthesize dihalocarbenes (Section 26.4), dichlorocarbene (CCL2)can be prepared by heating sodium trichloroacetate. Draw a stepwise mechanism for this reaction.

What starting material is needed to synthesize each compound by a ring-closing metathesis reaction?

a.

b.

c.

What ring-closing metathesis product is formed when each substrate is treated with Grubbs catalyst under high-dilution conditions?

a.

b.

c.
See all solutions

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