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Chapter 26: Q 16. (page 1066)

What product is formed by ring-closing metathesis of compound V, a key intermediate in the synthesis of ingenol, a natural product mentioned in the chapter opener?

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01

Ring-closing metathesis

Metathesis reactions, such as ring-closing metathesis reactions, occur in dilute solutions. Several natural products are produced with the help of metathesis reactions.

02

Ingenol

Ingenol is familiar with another name known as Picato. This substance occurs in the plant named Euphorbia peplus. It is known to cause skin cancer.

03

Product formed by the ring-closing metathesis of compound V

Alkene metathesis leads to the exchange of double bonds of carbon atoms. The product formed in the reaction consists of a ring structure comprising a double bond. The reaction of compound V with the Grubbs catalyst can be given as follows.

Ring-closing metathesis of compound V

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Most popular questions from this chapter

What products are formed when cis-pent-2-ene undergoes metathesis? Use this reaction to explain why metathesis of a 1, 2-disubstituted alkene (RCH=CHR') is generally not a practical method for alkene synthesis?

What steps are needed to convert but-1-ene \((C{H_3}C{H_2}CH = C{H_2})\) to octane \((C{H_3}{(C{H_2})_6}C{H_3})\)using a coupling reaction with an organocuprate reagent? All carbon atoms in octane mustcome from but-1-ene.

Dimethyl cyclopropanes can be prepared by the reaction of an 伪, 尾-unsaturated carbonyl compound X with two equivalents of a Wittig reagent Y. Draw a stepwise mechanism for this reaction.

Draw the product of each reaction.

Identify reagents A and B in the following reaction scheme. This synthetic sequence was used to prepare the C18 juvenile hormone (Figure 20.6).
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