Chapter 17: Q.66. (page 641)
Question: Explain why compound A is much more stable than compound B.

Short Answer
Answer
The aromaticity of compound A makes it more stable than compound B.
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Chapter 17: Q.66. (page 641)
Question: Explain why compound A is much more stable than compound B.

Answer
The aromaticity of compound A makes it more stable than compound B.
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Question: The purine heterocycle occurs commonly in the structure of DNA.

a. How is each N atom hybridized?
b. In what type of orbital does each lone pair on a N atom reside?
c. How many electrons does purine contain?
d. Why is purine aromatic?
Question: Hydrocarbon A possesses a significant dipole, even though it is composed of only C-C and C-H bonds. Explain why the dipole arises and use resonance structures to illustrate the direction of the dipole. Which ring is more electron rich?

Question: Use the inscribed polygon method to show the pattern of molecular orbitals in cyclonona-1,3,5,7-tetraene and use it to label its cation, radical, and anion as aromatic, antiaromatic, or not aromatic.

Question: Treatment of indene with forms its conjugate base in a Brønsted–Lowry acid-base reaction. Draw all reasonable resonance structures for indene’s conjugate base, and explain why the of indene is lower than the of most hydrocarbons.

Question: Explain why A is aromatic but B is not aromatic.

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