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Question: Explain why compound A is much more stable than compound B.

Short Answer

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Answer

The aromaticity of compound A makes it more stable than compound B.

Step by step solution

01

Stability of compounds

Numerous factors can influence the stability of a particular compound, and one among them is aromaticity.Aromatic compounds possess greater stability than anti-aromatic compounds.

02

Aromatic and anti-aromatic compounds

The count of pi electrons in aromatic compounds can be found using Huckle’s rule, and it comprises 4n+2π electrons. The count of pi electrons in anti-aromatic compounds is given by 4nπelectrons.

03

Stability of compound A and compound B

The second resonance structure of compound A indicates that the ring is completely conjugated and contains 6Ï€electrons leading them to become aromatic and a stable compound. The second resonance structure of compound A can be given as:

Second resonance structure of compound A

The charge-separated resonance structure of compound B provides the ring with 4Ï€electrons. Hence, the compound B is anti-aromatic and unstable. The second resonance structure of compound B can be given as:

Second resonance structure of compound B

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