91影视

Question: Which N atom in each compound is more basic? What product is formed when each compound is treated with HCl?

a.

b.

Question: Draw the products formed when each carbonyl compound reacts with the following amines:

1. CH₃CH₂CH₂NH₂

2.(CH₃CH₂)₂NH

a.

b.

c.

Question: Draw the product formed by treating each compound with excess CH₃I , followed by Ag₂O, and then heat.

a.

b.

c.

Question: Draw the major product formed in each reaction.

a.

b.

c.

d.

Question: Draw鈥倀he鈥俻roduct鈥俧ormed鈥倃hen鈥俥ach鈥俢ompound鈥俰s鈥倀reated鈥倃ith鈥侼aNO₂鈥俛苍诲鈥侣颁濒.

a.

b.

c.

d.

Question: Draw the product formed in each reaction.

a.

b.

c.

d.

Question: What starting materials are needed to synthesize each azo compound?

a.

b.

Question: Give a systematic or common name for each compound.

Question: Devise a synthesis of each compound from benzene. You may use any other organic or inorganic reagents.

a.

b.

c.

d.

e.

f.

Question: Safrole, which is isolated from sassafras (Problem 21.33), can be converted to the illegal stimulant MDMA (3,4-methylenedioxymethamphetamine, 鈥淓cstasy鈥�) by a variety of methods. (a) Devise a synthesis that begins with safrole and uses a nucleophilic substitution reaction to introduce the amine. (b) Devise a synthesis that begins with safrole and uses reductive amination to introduce the amine.