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Chapter 25: PROBLEM 25.24 (page 1023)

Question: Draw the products formed when each carbonyl compound reacts with the following amines:

1. CH3CH2CH2NH2

2.(CH3CH2)2NH

a.

b.

c.

Short Answer

Expert verified

Answer

a.

b.

c.

Step by step solution

01

Reaction of carbonyl compounds and the amines

The carbonyl compounds act as an electrophile in the presence of a Lewis base. The amines are the Lewis base because they contain lone pairs of electrons.

An amine gives its electron to the carbonyl group and forms a bond on the place of either the leaving group or the carbonyl oxygen.

02

Explanation

a. The reactions of hexanone with the given amine compounds CH3CH2CH2NH2and (CH3CH2)2NH are shown as:

Reactions of hexanone with CH3CH2CH2NH2and (CH3CH2)2NH

b.The reactions of anhydride with the given amine compounds and are shown as:

Reactions of anhydride withCH3CH2CH2NH2and (CH3CH2)2NH

c. The reactions of acyl chloride with the given amine compounds and are shown as:

Reactions of acyl chloride withCH3CH2CH2NH2and (CH3CH2)2NH

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