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Chapter 25: 49 (page 1043)

What carbonyl and nitrogen compounds are needed to make each compound by reductive amination? When more than one set of starting materials is possible, give all possible methods.

(a)

(b)

(c)

Short Answer

Expert verified

(a)

(b)

(c)

Step by step solution

01

Reductive amination

This reaction is used to convert carbonyl compounds to amines. It involves the formation of intermediate imine.

02

Explanation 

(a)

The carbonyl and nitrogen compounds that are needed to form by reductive amination are mentioned below.

Carbonyl and nitrogen compounds in a

(b)

The carbonyl and nitrogen compounds that are needed to form by reductive amination are mentioned below.

Carbonyl and nitrogen compounds in b

(c)

The carbonyl and nitrogen compounds that are needed to form by reductive amination are mentioned below.

Carbonyl and nitrogen compounds in c

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Most popular questions from this chapter

Question: Which nitrogen atom in each compound is more basic?

a.

b.

What amine is formed by reduction of each amide?

a.

b.

c.

Devise a synthesis of each compound from the given starting material(s). Albuterol is a bronchodilator and proparacaine is a local anesthetic.

(a)

(b)

Draw the products formed when p-methylaniline ( p-C6H4NH2) is treated with each reagent.

  1. HCl
  2. CH3COCl
  3. CH3CO2O
  4. Excess CH3I
  5. CH32C=O
  6. CH3COCl,AlCl3
  7. CH3CO2H
  8. NaNO2,HCl
  9. Part (b), thenCH3COCl,AlCl3
  10. CH3CHO,NaBH3CN

What amide(s) can be used to prepare each amine by reduction?

(a)

(b)

(c)
See all solutions

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