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Rank the following ions in the order of increasing basicity:

a.CH3C-H2,CH3O-,CH3N-H

b.CH3-,HO–,Br–

c.

d.

Short Answer

Expert verified

a. CH3O-<CH3N-H<CH3C-H2

b. Br–<HO–<CH3-

c. ClCH2COO-<CH3COO-<CH3CH2O-

d.

Step by step solution

01

Basicity

Basicityindicates the capability of a base to receive a proton. It can be linked with the pKa value of the particular conjugate acid.

02

Comparison of various compounds present in a

a. The strongest acid will possess the weakest conjugate base. The increasing acidity of conjugate acids is shown below

CH3CH3<CH3NH2<CH3OH

The ions in the order of increasing basicity are shown as follows:

CH3O-<CH3N-H<CH3C-H2

03

Comparison of various compounds present in b

b. The highly strong acid will have a weak conjugate base. The increasing acidity of conjugate acids can be given below

CH4<H2O<HBr

The ions in the order of increasing basicity are shown as follows:

Br–<HO–<CH3-

04

Comparison of various compounds present in c

c. Strong acids are regarded to possess a weak conjugate base. The increasing acidity of the conjugate acids can be given below:

CH3CH2OH<CH3COOH<ClCH2COOH

The ions in the order of increasing basicity are shown below:

ClCH2COO-<CH3COO-<CH3CH2O-

05

Comparison of various compounds present in c

d. The conjugate base of a strong acid is considered to be weak. The increasing acidity of the conjugate acid is shown below:

Acidity order of conjugate acids

The ions in the order of increasing basicity are shown below:

Basicity order of the compounds

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