Chapter 13: Q13-39E (page 419)
Predict the splitting pattern for each kind of hydrogen in isopropyl propanoate,.
Short Answer
Peaks produced are:
One singlet
Two quartet
Three septate
Four doublet
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Chapter 13: Q13-39E (page 419)
Predict the splitting pattern for each kind of hydrogen in isopropyl propanoate,.
Peaks produced are:
One singlet
Two quartet
Three septate
Four doublet
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Identify the indicated sets of protons as unrelated, homotopic, enantiotopic, or diastereotopic:
a.

b.

c.

How could you use and1H 13C NMR to help distinguish the following
isomeric compounds of the formula C4H8?

Question: 3-Bromo-1-phenyl-1-propene shows a complex NMR spectrum in which the vinylic proton at C2 is coupled with both the C1 vinylic proton (J = 16 Hz) and the C3 methylene protons (J = 8 Hz). Draw a tree diagram for the C2 proton signal, and account for the fact that a five-line multiplet is observed .

Propose structures for compounds that fit the following NMR data:
(a) C5H10O
0.95(6H,double, J = 7Hz)
2.10(3H,singlet)
2.43(1H, mutiplet)
(b) C3H5Br
2.32(3H,singlet)
5.35 (3H,singlet)
5.45(1H, broad signet )
Suppose you ran a DEPT-135 spectrum for each substance in Problem
13-47. Which carbon atoms in each molecule would show positive
peaks, and which would show negative peaks?
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