Chapter 13: Q13-39E (page 419)
Predict the splitting pattern for each kind of hydrogen in isopropyl propanoate,.
Short Answer
Peaks produced are:
One singlet
Two quartet
Three septate
Four doublet
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Chapter 13: Q13-39E (page 419)
Predict the splitting pattern for each kind of hydrogen in isopropyl propanoate,.
Peaks produced are:
One singlet
Two quartet
Three septate
Four doublet
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Estimate the chemical shift of each carbon in the following molecule. Predict which carbons will appear in the DEPT-90 spectrum, which will give positive peaks in the DEPT-135 spectrum, and which will give negative peaks in the DEPT-135 spectrum.
Draw structures for compounds that meet the following descriptions:
(a) C2H6O ; one singlet
(b) C3H7CI ; one doublet and one septet
(c) C4H8CI2O ; two triplets
(d) C2H8O ; one singlet, one triplet, and one quartet
Propose a structure for compound E, , which has the following NMR spectral data:
Compound E Broadband-decoupled NMR: 19.1, 28.0, 70.5, 129.0, 129.8, 165.8 DEPT-90: 28.0, 129.8 DEPT-135: positive peaks at 19.1, 28.0, 129.8 ; negative peaks at 70.5, 129.0
How many kinds of electronically non-equivalent protons are present in each of the following compounds, and thus how many NMR absorptions might you expect in each?
Calculate the amount of energy required to spin-flip a proton in a spectrometer operating at 300 MHz. Does increasing the spectrometer frequency from 200 to 300 MHz increase or decrease the amount of energy necessary for
resonance?
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