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Chapter 11: Q57b (page 350)

Question: Order each of the following sets of compounds with respect to reactivity:

b.

Short Answer

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Answer

Step by step solution

01

 SN2 reaction

It is a nucleophilic substitution reaction in which an old bond is broken and a new bond has formed both processes occur simultaneously. Hence, it鈥檚 a single-step reaction.

The two reacting species are involved in the rate-determining steps.

02

Reactivity towards SN2 reaction

As the reaction is the single-step reaction so, no intermediate is formed and occur fast with primary alkane than with secondary alkane.

SN2 occur fast with those reacting species which have best leaving group

SN2 occur fast when less steric hindrance occurs because if the steric hindrances more then reactivity get decrease.

So,

Reactivity order

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Most popular questions from this chapter

Question: Arrange the carbocations below in order of increasing stability.

a.

Question: Order each of the following sets of compounds with respect to reactivity:

b. (CH3)3 CCI (CH3)3 CBr (CH3)3 COH

Question:What products would you expect from the reaction of 1-bromopropane with each of the following?

(d) NaCN

What effect would you expect the following changes to have on the rate of thereaction of 1-iodo-2-methylbutane with cyanide ion?

(b) Both theand the 1-iodo-2-methylbutane concentrations are tripled.

Which substance in each of the following pairs is more reactive as a nucleophile? Explain.

(a)CH32N-orCH32NH(b) (CH3)3Bor(CH3)3N(c)H2OorH2S
See all solutions

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