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Chapter 11: Q56C (page 350)

Question: Order each of the following sets of compounds with respect to reactivity:

Short Answer

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Answer

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01

SN2  reaction

It is the substitution nucleophilic unimolecular reaction. It follows first-order kinetics that it is a two-step reaction in which a carbocation intermediate is formed.

The rate of the reaction depends only on the reacting species and is independent of the nucleophile.

02

Reactivity towards SN2 reaction

As the carbocation intermediate is formed in the reaction the reacting species which form the most stable carbocation is more reactive toward the nucleophile.

Stability of carbocation:

  1. 30 > 20 > 10
  2. If carbocation showing resonance is more stable than non-resonance carbocation

So,

Reactivity order

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Most popular questions from this chapter

3-Bromo-1-butene and 1-bromo-2-butene undergoSN1 reaction at nearly the same rate, even though one is a secondary halide and the other is primary. Explain.

d) Tell whether each of the following reactions is likely to be SN1, SN2, E1, E1cB or E2:

Predict whether each of the following substitution reactions is likely to be SN1orSN2:

(a)

(b)

Question:What products would you expect from the reaction of 1-bromopropane with each of the following?

(a) NaNH2

The following tertiary alkyl bromide does not undergo a nucleophilic substitution reaction by either SN1 or SN2 mechanisms. Explain.
See all solutions

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