Chapter 11: Q4 P. (page 319)
What product would you expect from reaction of 1-bromobutane with each of the following?
(a)NaI (b) KOH (c)(d)
Short Answer
(a)

(b)

(c)

(d)

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Chapter 11: Q4 P. (page 319)
What product would you expect from reaction of 1-bromobutane with each of the following?
(a)NaI (b) KOH (c)(d)
(a)

(b)

(c)

(d)

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What stereochemistry do you expect for the trisubstituted alkene obtained by E2 elimination of the following alkyl halide on treatment with KOH? (Reddish brown = Br.)

Which reactant in each of the following pairs is more nucleophilic? Explain.
(e) I- or Cl-
What product would you expect to obtain from reaction of with (R)-2-bromobutane? Show the stereochemistry of both the reactant and product.
Compound X is optically inactive and has the formula. On treatment with strong base, X gives hydrocarbon Y,. Compound Y absorbs 2 equivalents of hydrogen when reduced over a palladium catalyst and reacts with ozone to give two fragments. One fragment, Z, is an aldehyde with formula. The other fragment is glyoxal,. Write the reactions involved, and suggest structures for X, Y, and Z. What is the stereochemistry of X?
Which reactant in each of the following pairs is more nucleophilic? Explain.
d) (CH3)3P or (CH3)3N
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