91Ó°ÊÓ

These molecular species have at least one unpaired electron. Molecules normally consist of pairs of electrons.These are electron-deficient species.

• As radicals are electron deficient species. Their stability Increases with number of alkyl groups present on carbon bearing the free radical. So, radical stability increases in the order vinyl < methyl < primary < secondary < tertiary < allyl radical.
• Radicals Are Stabilized by resonance.

As the radical cannot move from its place due to no conjugation present on the adjacent position of the double bond .

RADICAL 1

It is a vinyl radical so least stable.

The radical cannot move from its position, since there is no conjugation at the adjacent position of the double bond.

RADICAL 2

It is a primary radical so less stable

The radical cannot move from its place since there are no conjugations present on the adjacent positions of the double bond.

RADICAL 3

It is secondary radical so among all three most stable