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Chapter 4: Q. 4-4-13P (page 104)

Draw two different chair conformations of trans-1,4 dimethylcyclohexane, and label all positions as axial or equatorial.

Short Answer

Expert verified

The two different chair conformations of trans-1,4 dimethylcyclohexane are:

Step by step solution

01

Chair confirmation

Chair conformation structure for a six-membered ring is when atoms 2, 3, 5, and 6 lie in the same plane, atom one lies above the plane, and atom 4 lies below the plane.

02

Axial and equatorial positions

Axial bonds are the bonds that are perpendicular or vertical to the ring plane. Equatorial bonds are approximately horizontal in the plane of the ring.

03

Structure of trans-1,4 dimethylcyclohexane: Axial

The two methyl groups and four hydrogens present are perpendicular or vertical to the ring plane.

The bond in pink represents axial bonds

04

Structure of trans-1,4 dimethylcyclohexane- equatorial

Here two methyl groups and four hydrogens are present approximately horizontal in the ring plane.

The bond in pink represent equatorial bonds

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Most popular questions from this chapter

How many H鈫�Heclipsing interactions would be present if cyclopentanewere planar? Assuming an energy cost of 4.0 kJ/mol for each eclipsing interaction,how much torsional strain would planar cyclopentane have? Since themeasured total strain of cyclopentane is 26 kJ/mol, how much of the torsionalstrain is relieved by puckering?

Hydrocortisone, a naturally occurring hormone produced in the adrenal glands, is often used to treat inflammation, severe allergies, and numerous other conditions. Is the indicated-OH group axial or equatorial?

Name the following substances, including the cis- or trans- prefix (red-brown= Br):

Draw structures corresponding to the following IUPAC names:

a) 1,1 dimethyl cyclooctane

b) 3-cyclobutyl hexane

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d) 1,2- dibromo, 5- methylcyclohexane

The following cyclohexane derivative has three red, green, and blue substituents. Identify each substituent as axial or equatorial, and identify each pair of relationships (red鈥揵lue, red-green, and blue-green) as cis or trans.
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