Q21E Predict the product and provide ... [FREE SOLUTION]

Chapter 20: Q21E (page 678)

Predict the product and provide the mechanism for each reaction below.

Short Answer

Expert verified

The product prediction and its mechanism for each of the reaction can be explained.

Step by step solution

Production prediction and mechanism for (a)

When bromobenzene treated with Mg in dry can yield the phenylmagnesium bromide. But treated with CO₂, will add nucleophile of Grignard reagent to carbonyl carbon. It leads to the production of intermediate compound on hydrolysis with aqueous acid. The product is Benzoic acid.

The formation mechanism can be denoted as,

Production prediction and mechanism for (b)

When 2-bromobutane treated with Mg in dry can yield the 2-butylmagnesium bromide. But treated with CO₂, will add nucleophile of Grignard reagent to carbonyl carbon. It leads to the production of intermediate compound on hydrolysis with aqueous acid. The product isButanoic acid.

The formation mechanism can be denoted as,

Production prediction and mechanism for (c)

When bromocyclopropane treated with Mg in dry can yield the propylmagnesium bromide. But treated with CO₂, will add nucleophile of Grignard reagent to carbonyl carbon. It leads to the production of intermediate compound on hydrolysis with aqueous acid. The product is Cyclopropanecarboxylic acid.

The formation mechanism can be denoted as,