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Chapter 23: Q23-3P (page 759)

What enone product would you expect from aldol condensation of each of the following compounds?

Short Answer

Expert verified

ENONEcontains饾泜鈥擆潧僽nsaturated carbonyl compound having alkene which is conjugated to ketone in the same compound.

Step by step solution

01

(a) first product is:

02

 Step 2: (b) second product is:

03

 Step 3: (c)third product is:

CH3-CH-CH2-C鈭�O-H+CH2CHO||CH3H3C-CH|CH3

EtOH鈫�鈫�NaOH

|OH||OCH3鈥�CH鈥�CH2鈥�C鈥�CH鈥�CH|||CH3HCH(CH3)2

鈫�鈫�heatrole="math" localid="1663308679621" (CH3)2-CH-CH2-CH=C-CHO|CH(CH3)2+H2O

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Most popular questions from this chapter

Predict the product(s) and provide the mechanism for each reaction below.

What product would you expect to obtain from the base treatment of

1,6-cyclo-decanedione?

The following reaction involves an intramolecular aldol reaction followed by a retroaldol-like reaction. Write both steps, and show their mechanisms.

What products would result after hydrolysis from the reaction of the enamineprepared from cyclopentanone and pyrrolidine with the following饾泜-饾泝-unsaturated acceptors?

(a)H2C=CHCO2Et

(b)H2C=CHCHO

(c)CH3CH=CHCOCH3

Which of the following compounds are aldol condensation products? What is the aldehyde or ketone precursor of each?

(a) 2-Hydroxy-2-methylpentanal (b) 5-Ethyl-4-methyl-4-hepten-3-one
See all solutions

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