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Chapter 6: Q8P. (page 165)

Add curved arrows to the following polar reactions to indicate the flow of electrons in each:

Short Answer

Expert verified

(a)

(b)

(c)

Step by step solution

01

Flow of electrons in the following reactions

(a)

If we observe the reaction, nitrogen chlorine bond is formed. Lone pair of electrons on nitrogen attacks chlorine so that bond gets a break.

Flow of electron shown

02

Breaking of C-Br bond

(b)

In the above reaction, negatively charged oxygen attacks the carbon so that the carbon and bromine bond gets a break. Methoxide ion reacts with methyl bromide to give dimethyl ether.

Flow of electron shown

03

Formation of C=O bond

(c)

In this reaction, the negative charge on oxygen gets delocalized and a carbon-oxygen double bond is formed and the carbon chlorine bond gets broken.

Flow of electron shown

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Most popular questions from this chapter

When a mixture of methane and chlorine is irradiated, a reaction commences immediately. When irradiation is stopped, the reaction gradually slows down but does not stop immediately. Explain.

Identify the following reactions as additions, eliminations, substitutions, or rearrangements:

a.

b.

c.

d.

Follow the flow of electrons indicated by the curved arrows in each of the following polar reactions, and predict the products that result:

Electrostatic potential maps of (a) formaldehyde (CH2O) and (b) methanethiol (CH3SH) are shown. Is the formaldehyde carbon atom likely to be electrophilic or nucleophilic? What about the methanethiol sulfur atom? Explain.

The addition of water to ethylene to yield ethanol has the following thermodynamic parameters:

(a) Is the reaction exothermic or endothermic?

(b) Is the reaction favorable (spontaneous) or unfavorable (nonspontaneous) at room temperature (298 K)?
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