Chapter 19: Q57E (page 648)
Draw structures of compounds that fit the following descriptions:
- An ,-unsaturated ketone,
- An -diketone
- An aromatic ketone,
- A diene aldehyde,
Short Answer
(a)

(b)

(c)

(d)

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Chapter 19: Q57E (page 648)
Draw structures of compounds that fit the following descriptions:
(a)

(b)

(c)

(d)

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Each of the following substances can be prepared by a nucleophilic
addition reaction between an aldehyde or ketone and a nucleophile.
Identify the reactants from which each was prepared. If the substance is an acetal, identify the carbonyl compound and the alcohol; if it is animine, identify the carbonyl compound and the amine; and so forth.

When crystals of pure -glucose are dissolved in water, isomerization occurs slowly to produce -glucose. Propose a mechanism for isomerization.

Show all the steps in the acid-catalyzed formation of a cyclic acetal from ethylene glycol and an aldehyde or ketone.
How might conjugate addition reactions of lithium diorganocopper reagents be used to synthesize the following compounds?

The amino acid methionine is biosynthesized by a multistep route thatincludes reaction of an imine of pyridoxal phosphate (PLP) to give anunsaturated imine, which then reacts with cysteine. What kinds ofreactions are occurring in the two steps?

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