91Ó°ÊÓ

The hydration of alkenes and the reduction of aldehydes, ketones, acids and esters leads to the formation of alcohols. The hydrolysis of halides can also generate alcohols. The hydroboration of alkenes can also generate alcohols.

(a)In this reaction, ethanol reacts with ${\mathrm{PBr}}_3$to form ethyl bromide. This product further reacts with Mg and ether to form ethyl magnesium bromide. This is the Grignard reagent used for the reaction.

Cyclohexanol reacts with ${\mathrm{CrO}}_3$and ${\mathrm{H}}_3{\mathrm{O}}^{+}$to form cyclohexanone. This further reacts with ethyl magnesium bromide and localid="1656436210972" ${\mathrm{H}}_3{\mathrm{O}}^{+}$to form the given compound 1-ethylcyclohexanol. The reaction can be given as:

Reaction (a)

(b)In this reaction, 2-methylpentan-1-ol reacts with localid="1656436216714" ${\mathrm{PBr}}_3$to form 1-bromo-2-methylpentane. This further reacts with Mg and ether to form (2-methylpentyl) magnesium bromide. This is used as the Grignard reagent.

Methanol reacts with Periodinane and localid="1656436223461" ${\mathrm{CH}}_2{\mathrm{Cl}}_2$to form formaldehyde. This further reacts with the Grignard reagent formed above in the presence of ether and localid="1656436229512" ${\mathrm{H}}_3{\mathrm{O}}^{+}$to form 3-methyl-hexan-1-ol. The reaction can be given as:

Reaction (b)

(c)Benzene reacts with ${\mathrm{Br}}_2$and ${\mathrm{FeBr}}_3$to form bromobenzene. This further reacts with Mg and ether to form phenyl magnesium bromide.

The alcohol, pentan-2-ol reacts with localid="1656436235665" ${\mathrm{CrO}}_3$and localid="1656436241025" ${\mathrm{H}}_3{\mathrm{O}}^{+}$to form pentan-2-one.

Phenyl magnesium bromide reacts with pentan-2-one in the presence of ether and localid="1656436246376" ${\mathrm{H}}_3{\mathrm{O}}^{+}$to form the compound 2-phenyl-pentan-2-ol. The reaction can be given as:

(d)The Grignard reagent used in this reaction is ethyl magnesium bromide.

The compound, 3-methylbutan-1-ol reacts with periodinane and localid="1656436292646" ${\mathrm{CH}}_2{\mathrm{CI}}_2$to form 3-methylbutanal. This compound reacts with ethyl magnesium bromide in the presence of ether and localid="1656436305787" ${\mathrm{H}}_3{\mathrm{O}}^{+}$to form 5-methylhexan-3-ol. The reaction can be given as:

Reaction (d)