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Chapter 1: Q74P (page 49)

Which compound has a larger dipole moment: CH3Cl or CH2Cl2?

Short Answer

Expert verified

Dipole moment of CHCl3 is greater than CH2Cl2 as all the bond moments are acting in the same direction in the former one.

Step by step solution

01

Definition of dipole moment

Dipole moment is defined as the multiplication of charge of an atom and the distance between the two atoms joined by a bond.

It is given as the formula.

Dipole moment=charge(e) X distance between two atoms (d)

02

Explanation of the dipole moment between two bonds

In case of CHCl3, all the bond moments acts on the same side, but for CH2Cl2, One C-H bond moment direction is opposite than the other three bonds moments of C-Cl and C-H. Which decreases te total dipole moment of the compound. So, the dipole moment for CHCl3 becomes greater than CH2Cl2.

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Most popular questions from this chapter

A tertiary amine reacts with hydrogen peroxide to form a tertiary amine oxide.

Tertiary amine oxides undergo a reaction similar to the Hofmann elimination reaction (Section 10.10), called a Cope elimination. In this reaction, a tertiary amine oxide, rather than a quaternary ammonium ion, undergoes elimination. A strong base is not needed for a Cope elimination because the amine oxide acts as its own base.

Does the Cope elimination have an alkene-like transition state or a carbanion-like transition state?

What is the hybridization of each of the carbon atoms in the following compound?

b. What is the hybridization of each of the C, N, and O atoms in Demerol and Prozac?(Generic names are not capitalized; trade names are capitalized.)

Demerol庐 : used to treat moderate to severe pain

Prozac: used to treat depression, obsessive-compulsive disorder, some eating disorders, and panic attacks

Which of the bonds in a carbon-oxygen double bond has more effective orbital overlap: the bond 蟽 or the bond 蟺 ?

How many valence electrons do the following atoms have?

  1. Boron 2. nitrogen 3. oxygen 4. Fluorine

Use the symbol 未+and 未+to show the direction of polarity of the indicated bonds in each of the following compounds:
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