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Chapter 15: Q34. (page 570)

Question: Draw all constitutional isomers formed by monochlorination of each alkane with Cl2 and hv.

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01

Constitutional isomers

The organic compounds with the same molecular formula but different structural arrangements of the constituent elements are known as the constitutional isomers.

02

Monochlorination

The organic reaction involving the replacement of a loosely held hydrogen atom by a chlorine atom initiated by light energy is known as chlorination.

Consider the monochlorination of the given compounds,

a. In 2,2-dimethylhexane five different types of H atom are present that would give five constitutional isomers.


Monochlorination reaction

b. In n-heptane, four different H atom is present that would give rise to four constitutional isomers.


Constitutional isomers

c. In methyl cyclopropane, there are four possible constitutional isomers as follows,


Constitutional isomers of methyl cyclopropane

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Most popular questions from this chapter

Question: Consider the following Bromination:

(CH)3 CH +Br2鈫�鈭�(CH3)3 CBr +HBr

(a) Calculate 螖H掳 for this reaction by using the bond dissociation energies in Table 6.2. (b) Draw out a stepwise mechanism for the reaction, including the initiation, propagation, and termination steps. (c) Calculate 螖H掳 for each propagation step. (d) Draw an energy diagram for the propagation steps. (e) Draw the structure of the transition state of each propagation step.

Question: Draw the product(s) formed when each alkene is treated with either [1] HBr alone; or [2] HBr in the presence of peroxides.

a.

b.

c.

Question: Devise a synthesis of each compound from cyclopentane and any other required organic or inorganic reagents.

a.

b.

c.

d.

e.

Question: Draw the products of each reaction.

a.

b.

c.

Questions: Compounds A and B are isomers having molecular formula C5H12. Heating A with Cl2 gives a single product of monohalogenation, whereas heating B under the same conditions forms three constitutional isomers. What are the structures of A and B?
See all solutions

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