/*! This file is auto-generated */ .wp-block-button__link{color:#fff;background-color:#32373c;border-radius:9999px;box-shadow:none;text-decoration:none;padding:calc(.667em + 2px) calc(1.333em + 2px);font-size:1.125em}.wp-block-file__button{background:#32373c;color:#fff;text-decoration:none} Q34. Question: Draw all constitutiona... [FREE SOLUTION] | 91影视

91影视

Log out

Learning Materials

Features

Discover

Chapter 15: Q34. (page 570)

Question: Draw all constitutional isomers formed by monochlorination of each alkane with Cl2 and hv.

Short Answer

Expert verified

Answer

Step by step solution

01

Constitutional isomers

The organic compounds with the same molecular formula but different structural arrangements of the constituent elements are known as the constitutional isomers.

02

Monochlorination

The organic reaction involving the replacement of a loosely held hydrogen atom by a chlorine atom initiated by light energy is known as chlorination.

Consider the monochlorination of the given compounds,

a. In 2,2-dimethylhexane five different types of H atom are present that would give five constitutional isomers.


Monochlorination reaction

b. In n-heptane, four different H atom is present that would give rise to four constitutional isomers.


Constitutional isomers

c. In methyl cyclopropane, there are four possible constitutional isomers as follows,


Constitutional isomers of methyl cyclopropane

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with 91影视!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

Question: The triphenylmethyl radical is an unusual persistent radical present in solution in equilibrium with its dimer. For 70 years the dimer was thought to be hexaphenylethane, but in 1970, NMR data showed it to be A.

a. Why is the triphenylmethyl radical more stable than most other radicals?

b. Use curved arrow notation to show how two triphenylmethyl radicals dimerize to form A.

c. Propose a reason for the formation of A rather than hexaphenylethane.d. How could 1 H and 13C NMR spectroscopy be used to distinguish between hexaphenylethane and A?

Questions: Draw all constitutional isomers formed by monochlorination of each alkane.

a.

b.

c.

Question: Identify the structure of a minor product formed from the radical chlorination of propane, which has molecular formula C3H6Cl2 and exhibits the given 1H NMR spectrum.

Questions: Rank the indicated hydrogen atoms in order of increasing ease of abstraction in a radical halogenation reaction.

Question: Five isomeric alkanes (A鈥揈) having the molecular formula C6H14 are each treated with Cl2 + hv to give alkyl halides having molecular formula C6H13Cl . A yields five constitutional isomers. B yields four constitutional isomers. C yields two constitutional isomers. D yields three constitutional isomers, two of which possess stereo-genic centres. E yields three constitutional isomers, only one of which possesses a stereo-genic centre. Identify the structures of A鈥揈.
See all solutions

Recommended explanations on Chemistry Textbooks

Chemical Reactions

Read Explanation

Kinetics

Read Explanation

Organic Chemistry

Read Explanation

Chemistry Branches

Read Explanation

Inorganic Chemistry

Read Explanation

Physical Chemistry

Read Explanation
View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.