Chapter 31: Question 31.3 (page 1237)
Draw the products formed when triacylglycerol A is treated with each reagent. Rank compounds A, B and C in order of increasing melting point.
a.,
b. (excess),
c.(1 equiv),
Short Answer
Answer
a.

b.

c.

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Chapter 31: Question 31.3 (page 1237)
Draw the products formed when triacylglycerol A is treated with each reagent. Rank compounds A, B and C in order of increasing melting point.
a.,
b. (excess),
c.(1 equiv),
Answer
a.

b.

c.

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Locate the isoprene units in each compound.
a.

b.

c.

d.

Treatment of cholesterol with mCPBA results in formation of a single epoxide A, with the stereochemistry drawn. Why isn’t the isomeric epoxide B formed to any extent?

Draw a stepwise mechanism for the following conversion, which forms camphene. Camphene is a component of camphor and citronella oils.

A flask contains 1/3 mole of H2 and 2/3 mole of He. Compare the force on the wall per impact of H2 relative to that for He.
Draw all possible constitutional isomers of a triacylglycerol formed from one mole each of palmitic, oleic, and linoleic acids. Locate the tetrahedral stereogenic centers in each constitutional isomer.
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