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Question: (a)Identify the functional groups in salinosporamide A, an anticancer agent isolated from marine sediment.(b)Classify each alcohol, alkyl halide, amide, and amine as 10,20, or 30.

Short Answer

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Answer

(a) The functional groups in salinosporamide A are alkene, alcohol, amide, alkyl halide, and cyclic ester.

(b)Salinosporamide A comprises secondary alcohol, primary alkyl halide, and secondary amide.

Step by step solution

01

Functional group

Specific functional groups are responsible for the initiation of several organic reactions.Numerous functional groups are present, and some of them include alcohol, alkyl halide, and ester.

02

Classification of compounds into 10,20, or 30

If a functional group like alcohol is linked to one carbon atom,then isa primary alcohol. A functional group can be categorized into secondary, and tertiary based on its linkage to the carbon atoms.

03

Identification of functional groups in salinosporamide A

The functional groups in salinosporamide A are alkene, alcohol, amide, alkyl halide, and cyclic ester. The structure of salinosporamide A, along with the functional groups, is shown below:

Functional groups in salinosporamide A

04

Classification of alcohol and alkyl halide into 10,20, or 30

The given structure comprises secondary alcohol as the alcohol is linked to two carbon atoms. It also contains a primary alkyl chloride as the chloride atom is linked to one carbon atom.

The representation of secondary alcohol and primary alkyl chloride is given below:

Representation of alcohol and alkyl chloride

The amide present in the compound is secondary amide as the nitrogen atom is linked to two carbon atoms in the structure. The representation of the amide is given below:

Representation of amide

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Most popular questions from this chapter

Question: Intramolecular forces of attraction are often important in holding large molecules together. For example, some proteins fold into compact shapes, held together by attractive forces between nearby functional groups. A schematic of a folded protein is drawn here, with the protein backbone indicated by a blue-green ribbon, and various appendages drawn dangling from the chain. What types of intramolecular forces occur at each labeled site (A–F)?

Question: Predict the water solubility of each of the following organic molecules.

a.

b.

c.

d.

Question: Many drugs are sold as their hydrochloride salts (R2NH2+Cl-), formed by reaction of an amine (R2NH2)with HCl.

a. Draw the product (a hydrochloride salt) formed by reaction of acebutolol with HCl. Acebutolol is a β blocker used to treat high blood pressure. b. Discuss the solubility of acebutolol and its hydrochloride salt in water. c. Offer a reason as to why the drug is marketed as a hydrochloride salt rather than a neutral amine.

Question: Draw structures that fit each description and name the functional group in each molecule:

  1. two constitutional isomers with molecular formula C5H10O that contain different functional groups;
  2. two constitutional isomers with molecular formula C6H10O that contain the same functional group.

Question: The composition of a cell membrane is not uniform for all types of cells. Some cell membranes are more rigid than others. Rigidity is determined by a variety of factors, one of which is the structure of the carbon chains in the phospholipids that comprise the membrane. One example of a phospholipid was drawn in Section 3.7A, and another, having C-C double bonds in its carbon chains, is drawn here. Which phospholipid would be present in the more rigid cell membrane and why?

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